Sigma Phase Guide: Embrittlement in Stainless & Duplex Weldments

Sigma Phase Guide: Embrittlement in Stainless & Duplex Weldments

Short answer: Sigma phase is a hard, brittle intermetallic that forms in stainless and duplex steels when held in the 550-950°C range — especially in welded or high-ferrite material — embrittling the joint. Control chemistry, heat input and post-weld treatment to avoid it.

At a Glance

Sigma Phase Guide: Embrittlement in Stainless & Duplex Weldments chart
Figure 1 – Sigma Phase Guide: Embrittlement in Stainless & Duplex Weldments overview.

Where Sigma Forms

High ferrite and slow cooling in Duplex Stainless Steel Guide y Duplex Vs Super Duplex raise risk; context in Grados de acero inoxidable explicados y Ferritic Vs Austenitic Stainless.

Weld Control

Limit heat input and interpass temperature; manage Metal Welding Distortion Guide and inspect Weld Defects Guide under Metal Metallography Guide with Metal Ndt Guide.

QA & Supply

Document chemistry and thermal history per Mill Test Certificate Guide. HXSCO supplies low-sigma-risk grades.

Get a Quote

Tell HXSCO your requirements and we will respond with a competitive quote and lead time.

Preguntas frecuentes

What is sigma phase?

A brittle Fe-Cr intermetallic that embrittles stainless/duplex steel.

When does it form?

Holding in roughly 550-950°C, common in slow-cooled welds.

Which alloys are most at risk?

Duplex and high-ferrite grades are most sensitive.

How do you avoid it?

Control heat input, ferrite and post-weld cooling.

Do you supply low-sigma grades?

HXSCO supplies grades selected to limit sigma-phase risk.

Source Low-Sigma Stainless from HXSCO

HXSCO supplies duplex and austenitic grades selected to limit sigma-phase embrittlement. Send your service and quantity for a quote.

Request a Quote